THE 1ST EXAMPLE OF A DISCRETE THIOCYANATOCUPRATE(I) ANION - CRYSTAL-STRUCTURE OF BIS[6-AMINO-1,3-DIMETHYL-5-(2'-ETHYL)PHENYLAZONIUM URACIL] TRIS(THIOCYANATO-S)-CUPRATE(I)

被引：10

作者：

KIVEKAS, R ^{[1
]}

RUIZ, J ^{[1
]}

COLACIO, E ^{[1
]}

机构：

[1] UNIV GRANADA,FAC CIENCIAS,DEPT QUIM INORGAN,E-18071 GRANADA,SPAIN

来源：

ACTA CHEMICA SCANDINAVICA | 1994年 / 48卷 / 05期

关键词：

D O I：

10.3891/acta.chem.scand.48-0382

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The crystal structure of the title compound [H2L]2[Cu(SCN)3] (where H2L+ is the 6-amino-1,3-dimethyl-5(2'-ethyl)phenylazonium uracil cation] was determined by X-ray crystallography. The compound crystallizes in the monoclinic system, space group P2(1), with a = 7.740(3), b = 40.09(3), c = 11.950(7) angstrom, beta = 97.11(4)-degrees, Z = 4, R = 0.125, wR = 0.108. The structure consists of discrete [Cu(SCN)3]2-anions and H2L+ cations joined together by hydrogen bonds. There are two non-equivalent tris(thiocyanato-S)cuprate(I) anions in the structure. In each anion the copper(I) atom is coordinated to the sulfur atoms of the three thiocyanate anions in a distorted trigonal planar configuration.

引用

页码：382 / 387

页数：6

共 17 条

[1]

[Anonymous], [No title captured]

[2] TRIS-(1-METHYLIMIDAZOLINE-2(3H)-THIONE)COPPER(I) NITRATE - PREPARATION, THERMAL-ANALYSIS AND CRYSTAL-STRUCTURE [J].

ATKINSON, ER ;

GARDINER, DJ ;

JACKSON, ARW ;

RAPER, ES .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 98 (01) :35-41

[3] THE 1ST AMBIENT PRESSURE ORGANIC SUPERCONDUCTOR CONTAINING OXYGEN IN THE DONOR MOLECULE, BETA-M-(BEDO-TTF)3CU2(NCS)3, TC=1.06 K [J].

BENO, MA ;

WANG, HH ;

KINI, AM ;

CARLSON, KD ;

GEISER, U ;

KWOK, WK ;

THOMPSON, JE ;

WILLIAMS, JM ;

REN, JQ ;

WHANGBO, MH .

INORGANIC CHEMISTRY, 1990, 29 (09) :1599-1601

[4]

CARLSON KD, 1988, INORG CHEM, V27, P2904, DOI 10.1021/ic00289a036

[5] SYNTHESIS, ELECTRON-SPIN-RESONANCE STUDIES, BAND ELECTRONIC-STRUCTURE, AND SUPERCONDUCTIVITY IN THE (BEDT-TTF)2CU(NCS)2, (BEDT-TTF)2AG(NCS)2, (BEDT-TTF)2AU(NCS)2 SYSTEM [J].

CARLSON, KD ;

GEISER, U ;

KINI, AM ;

WANG, HH ;

MONTGOMERY, LK ;

KWOK, WK ;

BENO, MA ;

WILLIAMS, JM ;

CARISS, CS ;

CRABTREE, GW ;

WHANGBO, MH ;

EVAIN, M .

INORGANIC CHEMISTRY, 1988, 27 (06) :965-967

[6] THE CRYSTAL-STRUCTURES AND PHYSICAL-PROPERTIES OF POLYMERIC (BEDT-TTF)-METALLOTHIOCYANATES [J].

GEISER, U ;

BENO, MA ;

KINI, AM ;

WANG, HH ;

SCHULTZ, AJ ;

GATES, BD ;

CARISS, CS ;

CARLSON, KD ;

WILLIAMS, JM .

SYNTHETIC METALS, 1988, 27 (1-2) :A235-A241

[7]

HALL SR, 1987, XTAL2 6 USERS MANUAL

[8] CRYSTAL-STRUCTURE OF COPPER(I) THIOCYANATE AND ITS RELATION TO CRYSTAL-STRUCTURE OF COPPER(II) DIAMMINE DITHIOCYANATE COMPLEX [J].

KABESOVA, M ;

DUNAJJURCO, M ;

SERATOR, M ;

GAZO, J ;

GARAJ, J .

INORGANICA CHIMICA ACTA, 1976, 17 (02) :161-165

[9] CHLOROGOLD(I) AND GOLD(III) COMPLEXES OF 6-AMINO-1,3-DIMETHYL-5-ARYLAZOURACIL DERIVATIVES - IR SPECTROSCOPY, GROWTH-INHIBITION OF HELA-CELLS AND X-RAY CRYSTAL-STRUCTURE OF 6-AMINO-1,3-DIMETHYL-5-PHENYLAZONIUMURACIL DICHLOROAURATE(I) SESQUIHYDRATE [J].

KIVEKAS, R ;

COLACIO, E ;

RUIZ, J ;

LOPEZGONZALEZ, JD ;

LEON, P .

INORGANICA CHIMICA ACTA, 1989, 159 (01) :103-110

[10] 6-AMINO-1,3-DIMETHYL-5-(2-ETHYLPHENYLAZONIO)URACIL BROMIDE DIHYDRATE [J].

KIVEKAS, R ;

SUNDBERG, MR ;

RUIZ, J ;

COLACIO, E .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :1512-1515

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