1,8-DIAZABICYCLO[5.4.0]UNDEC-7-ENE AS A DIFUNCTIONAL NUCLEOPHILE

被引：35

作者：

CHAMBERS, RD

ROCHE, AJ

BATSANOV, AS

HOWARD, JAK

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 18期

关键词：

D O I：

10.1039/c39940002055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

DBU 1 reacts as a (1,3) difunctional nucleophile with 2-H heptafluorobut-2-ene 2, giving the unusual product 8;a mechanism for the formation of 8 is proposed and an X-ray crystal structure of 8 is described.

引用

页码：2055 / 2056

页数：2

共 4 条

[1] PYRAZOLE STUDIES .20. NUCLEOPHILIC BEHAVIOR OF DBU AND DBN IN REACTIONS WITH 4-HALO-3,5-DIMETHYL-1-NITRO-1H-PYRAZOLES
LAMMERS, H
COHENFERNANDES, P
HABRAKEN, CL
[J]. TETRAHEDRON, 1994, 50 (03) : 865 - 870
[2] 3-MEMBERED RINGS .8. REACTION OF 1-HALOCYCLOPROPANE 1,2-DIESTERS WITH 1,8-DIAZABICYCLO[5.4.0]UNDEC-7-ENE - UNEXPECTED PRODUCTS
MCCOY, LL
MAL, D
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (05) : 1016 - 1018
[3] OEDIGER H, 1972, SYNTH-INT J METHODS, P591
[4] DBU AND DBN ARE STRONG NUCLEOPHILES - X-RAY CRYSTAL-STRUCTURES OF ONIO-SUBSTITUTED AND DIONIO-SUBSTITUTED PHOSPHANES
REED, R
REAU, R
DAHAN, F
BERTRAND, G
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (03): : 399 - 401

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