XAFS STUDY OF SHORT-RANGE ORDER IN THE HEAVILY DISORDERED MOXW1-XO3 OXIDES

被引：7

作者：

PURANS, J

KUZMIN, A

PARENT, P

DEXPERT, H

机构：

[1] UNIV LATVIA, INST SOLID STATE PHYS, RIGA, LATVIA

[2] UNIV PARIS 11, LURE, F-91405 ORSAY, FRANCE

来源：

PHYSICA B | 1995年 / 208卷 / 1-4期

关键词：

D O I：

10.1016/0921-4526(94)00699-V

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

We have done comparative XAFS analysis on the Mo K and W L(3) edges of polycrystalline MO(x)W(1-x)O(3) solid solutions. It was found that their structures are closely related to corner-shared WO3-type for x < 0.9 while alpha-MoO3-type structure is present for x greater than or equal to 0.9. The obtained structural parameters for the first shell around metal ions allow to distinguish several structural phase transitions due to the change of composition. A set of subshells within the first shell was found, and they are in good agreement with Raman data.

引用

页码：373 / 374

页数：2

共 6 条

[1] NEW OXIDES IN THE WO3-MOO3 SYSTEM
FIGLARZ, M
[J]. PROGRESS IN SOLID STATE CHEMISTRY, 1989, 19 (01) : 1 - 46
[2] ELECTROCHROMISM AND SMART WINDOW DESIGN
GRANQVIST, CG
[J]. SOLID STATE IONICS, 1992, 53 : 479 - 489
[3] INFLUENCE OF THE FOCUSING EFFECT ON XAFS IN REO3, WO3-X AND FEF3
KUZMIN, A
PURANS, J
PARENT, P
[J]. PHYSICA B, 1995, 208 (1-4): : 45 - 46
[4] EDA - EXAFS DATA-ANALYSIS SOFTWARE PACKAGE
KUZMIN, A
[J]. PHYSICA B, 1995, 208 (1-4): : 175 - 176
[5] A NEW FAST SPHERICAL APPROXIMATION FOR CALCULATION OF MULTIPLE-SCATTERING CONTRIBUTIONS IN X-RAY ABSORPTION FINE-STRUCTURE AND ITS APPLICATION TO REO3, NAWO3 AND MOO3
KUZMIN, A
PURANS, J
[J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 1993, 5 (03) : 267 - 282
[6] STRUCTURAL PHASE-TRANSITION IN MIXED-CRYSTALS WXMO1-XO3
SALJE, E
GEHLIG, R
VISWANATHAN, K
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1978, 25 (03) : 239 - 250

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