ISOLATION, IDENTIFICATION, AND CHROMATOGRAPHIC CHARACTERIZATION OF SOME CHLORINATED C10 HYDROCARBONS IN TECHNICAL CHLORDANE

被引：28

作者：

PARLAR, H ^{[1
]}

HUSTERT, K ^{[1
]}

GAB, S ^{[1
]}

KORTE, F ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST CHEM,D-8050 FREISING,FED REP GER

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 1979年 / 27卷 / 02期

关键词：

D O I：

10.1021/jf60222a015

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

With the help of column chromatography, three new substances, l-exo, 4, 5, 7, 8, 8-hexachloro-3a, 4,- 7, 7a-tetrahydro-4, 7-methanoindene (8), l-exo, 2-exo, 4, 5, 7, 8, 8-heptachloro-3a, 4, 7, 7a-tetrahydro-4, 7-methanoindane (15), and l-exo, 2-exo, 4, 6, 7, 8, 8-heptachloro-3a, 4, 7, 7a-tetrahydro-4, 7-methanoindane (16), were isolated from technical chlordane and were identified by spectroscopic methods (mass spectrometry, infrared, and 1H NMR). These compounds could be synthesized by photochemical dechlorination of heptachlor (11) and of α-(or cis-) chlordane (17) in methanol. In addition, the mixture was investigated by capillary gas chromatography and by combined gas chromatography and mass spectrometry. The data obtained were used to characterize the composition of technical chlordane. © 1979, American Chemical Society. All rights reserved.

引用

页码：278 / 283

页数：6

共 22 条

[1]

BIENIEK D, 1970, TETRAHEDRON LETT, V47, P4055

[2] CYCLODIEN-INSEKTIZIDE .4. SYNTHESE UND STRUKTUR VON ISOMEREN DES CHLORDANS [J].

BUCHEL, KH ;

GINSBERG, AE ;

FISCHER, R .

CHEMISCHE BERICHTE-RECUEIL, 1966, 99 (02) :421-&

[3]

COCHRANE WP, 1976, J ASSOC OFF ANA CHEM, V59, P696

[4]

COCHRANE WP, 1974, COMMUNICATION

[5]

COCHRANE WP, 1975, J AGR FOOD CHEM, V23, P883

[6]

FALBE J, 1967, CHEM ZTG, V91, P79

[7]

GAB S, 1977, J AGR FOOD CHEM, V25, P1365

[8]

GAB S, 1977, J AGR FOOD CHEM, V25, P1224

[9]

GAB S, 1976, J LIEBIG ANN CHEM, V1

[10]

GAB S, UNPUBLISHED

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