GENERALIZED GOLDEN-RULE TREATMENT OF A PHOTOCHEMICAL SOLID-STATE REACTION INVOLVING HYDROGEN TUNNELING

被引：25

作者：

LAVTCHIEVA, L

SMEDARCHINA, Z

机构：

[1] Institute of Organic Chemistry, Bulgarian Academy of Sciences

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 184卷 / 5-6期

关键词：

D O I：

10.1016/0009-2614(91)80032-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Fast photochemical H- and D-transfer in acridine doped fluorene crystals is treated as multidimensional tunneling. Both the stretching and bending vibrations of the transferred atom and the lattice phonons which affect the tunneling distance are taken into account. The golden rule approach is applied as generalized for arbitrary values of the electronic coupling integral, as reported earlier. Its relatively large value is found to be the main reason for the unusually rapid reaction.

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页码：545 / 552

页数：8

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