[HG7(SC6H11)12BR2], A NOVEL MERCURY CAGE MOLECULE WITH BRIDGING AND TERMINAL THIOLATE LIGANDS AND WITH TERMINAL AND MU-6 BROMIDE

被引：11

作者：

ALSINA, T

CLEGG, W

FRASER, KA

SOLA, J

机构：

[1] UNIV NEWCASTLE UPON TYNE, DEPT CHEM, Newcastle Upon Tyne NE1 7RU, TYNE & WEAR, ENGLAND

[2] UNIV AUTONOMA BARCELONA, DEPT QUIM, E-08193 BARCELONA, SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 14期

关键词：

D O I：

10.1039/c39920001010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of HgBr2 with sodium cyclohexanethiolate in methanol, followed by recrystallisation from pyridine, gives the discrete molecular complex [Hg7(SC6H11)12Br2], in which six Hg atoms form a distorted octahedron around a central Br, thiolate ligands are bridging or terminal, and a HgBr unit with terminal Br caps three thiolates on one side of the molecule.

引用

页码：1010 / 1011

页数：2

共 37 条

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