N-BENZYL-3-(TRI-NORMAL-BUTYLSTANNYL)THIOPROPIONAMIDE AS THIOHOMOENOLATE SYNTHON - APPLICATION TO A SYNTHESIS OF SOME HETEROCYCLES

被引：11

作者：

TAKAHATA, H

OHKURA, E

IKURO, K

YAMAZAKI, T

机构：

[1] Faculty of Pharmaceutical Sciences, , Toyama Medical & Pharmaceutical Universit, 2630 Sugitani Toyama

来源：

SYNTHETIC COMMUNICATIONS | 1990年 / 20卷 / 02期

关键词：

D O I：

10.1080/00397919008052296

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Benzyl-3-(tri-n-butylstannyl)thiopropionamide undergoes metal-exchange with n-butylhthium. The resulting thiohomoenolate dianion reacts with electrophiles (aldehydes and ketones) to give the y-hydroxythioamides, which are transformed into lactones, iminothiolactones, and thiolactams with simple elaboration. Copyright © 1990 by Taylor & Francis Group. All rights reserved.

引用

页码：285 / 292

页数：8

共 18 条

[1] THIONATION REACTIONS OF LAWESSON REAGENTS [J].