RHODIUM(II) CARBOXYLATE-CATALYZED REACTIONS OF DIAZOESTERS - EVIDENCE FOR AN EQUILIBRIUM BETWEEN FREE CARBENE AND A METAL-CARBENE COMPLEX

被引：51

作者：

DEMONCEAU, A

NOELS, AF

COSTA, JL

HUBERT, AJ

机构：

[1] UNIV LIEGE,MACROMOLEC CHEM & ORGAN CATALYSIS LAB,B-4000 LIEGE,BELGIUM

[2] UNIV LIEGE,ORGAN SYNTH & CATALYSIS LAB,B-4000 LIEGE,BELGIUM

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1990年 / 58卷 / 01期

关键词：

D O I：

10.1016/0304-5102(90)85176-I

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A comparative study of alkane functionalisation by ethyl diazoacetate and diethyl diazomalonate, catalysed by various rhodium(II) carboxylates, indicates that different reactive species, presumably a metal-carbene intermediate and the 'free' carbene, are involved in the reaction. © 1990.

引用

页码：21 / 26

页数：6

共 29 条

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