PREPARATION AND X-RAY CRYSTAL-STRUCTURES OF VOLATILE COPPER(II) ALKOXIDES

被引：82

作者：

GOEL, SC ^{[1
]}

KRAMER, KS ^{[1
]}

CHIANG, MY ^{[1
]}

BUHRO, WE ^{[1
]}

机构：

[1] WASHINGTON UNIV,DEPT CHEM,ST LOUIS,MO 63130

来源：

POLYHEDRON | 1990年 / 9卷 / 04期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0277-5387(00)86241-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Volatile amino-alkoxide complexes Cu[OCH2CH2NMe2]2 (1), Cu[OCHMeCH2 NMe2]2 (2) and Cu[OCH2CH2NMeCH2CH2NMe2]2 (3) have been prepared. X-ray crystal structures reveal a mononuclear, square-planar geometry for 2, and a mononuclear, distorted, square-pyramidal geometry for 3. Thermal decomposition (25-300°C) of 1 gives a mixture of copper, CuO and Cu2O whereas thermal decomposition of 2 gives copper. © 1990.

引用

页码：611 / 613

页数：3

共 23 条

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