SYNTHESIS OF NATURALLY-OCCURRING (-)-DELTA-9(12)-CAPNELLENE AND ITS ANTIPODE - AN APPLICATION OF THE PHOTOINDUCED VINYLCYCLOPROPANE-CYCLOPENTENE REARRANGEMENT

被引：20

作者：

SONAWANE, HR

NANJUNDIAH, BS

SHAH, VG

KULKARNI, DG

AHUJA, JR

机构：

[1] National Chemical Laboratory, Pune

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 08期

关键词：

D O I：

10.1016/S0040-4039(00)74500-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Abundantly available (+)-DELTA-3-Carene, 1 has been transformed into enantiomerically pure key intermediates viz. the enones (-)-7 and (+)-7, thus constituting a formal synthesis of both the enantiomers of DELTA-9(12)-Capnellene.

引用

页码：1107 / 1108

页数：2

共 8 条

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[2] AN EFFICIENT, ENANTIOCONVERGENT TOTAL SYNTHESIS OF NATURAL HIRSUTIC ACID-C
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[3] MARVELL, 1971, CHEM HYDROXYL GROUP, P719
[4] ASYMMETRIC TOTAL SYNTHESIS OF (+)-DELTA-9(12)-CAPNELLENE
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[5] ORGANOTIN-BASED BIFUNCTIONAL REAGENTS - 4-CHLORO-2-LITHIO-1-BUTENE AND RELATED SUBSTANCES - METHYLENECYCLOPENTANE ANNULATIONS - TOTAL SYNTHESIS OF (+/-)-DELTA-9(12)-CAPNELLENE
PIERS, E
KARUNARATNE, V
[J]. TETRAHEDRON, 1989, 45 (04) : 1089 - 1104
[6] SONAWANE HR, 1983, TETRAHEDRON LETT, P3971
[7] SONAWANE HR, 1985, TETRAHEDRON LETT, P1097
[8] SONAWANE HR, 1984, TETRAHEDRON LETT, P2245

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