SYNTHESIS AND CHARACTERIZATION OF [RU5C(CO)11(MU-2-ETA-2-ETA-2-C6H8-1,4)2] - THE 1ST EXAMPLE OF CYCLOHEXA-1,4-DIENE IN A BRIDGING COORDINATION MODE

被引：8

作者：

DYSON, PJ

JOHNSON, BFG

LEWIS, J

BRAGA, D

SABATINO, P

机构：

[1] UNIV EDINBURGH,DEPT CHEM,W MAINS RD,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

[2] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

[3] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40136 BOLOGNA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 03期

关键词：

D O I：

10.1039/c39930000301

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The molecular structure of the square-pyramidal cluster [Ru5C(CO)11(mu2-eta2:eta2-C6H8-1,4)2] has been established by single crystal X-ray analysis; the coordination mode is unique for the two cyclohexa-1,4-diene ligands, each bridging two ruthenium atoms.

引用

页码：301 / 302

页数：2

共 10 条

[1]

BAILEY PJ, IN PRESS J CHEM S DA

[2]

BOEKELHEIDE V, 1986, J AM CHEM SOC, V108, P3324

[3] REACTION OF [OS4(MU-H)4(CO)12] WITH CYCLOHEXA-1,3-DIENE VIA CHEMICAL ACTIVATION - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [OS4(MU-H)2(CO)10(ETA-6-C6H6)] AND [OS4(CO)9(ETA-6-C6H6)(ETA-4-C6H8)] AND THEIR INTERCONVERSION [J].