A DSC STUDY OF INTRAZEOLITE COPPER(II) PHTHALOCYANINE FORMATION

被引：11

作者：

FERRARIS, JP

BALKUS, KJ

SCHADE, A

机构：

[1] Department of Chemistry, University of Texas at Dallas, Richardson, 75083-0688, TX

来源：

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1992年 / 14卷 / 02期

关键词：

ZEOLITE; PHTHALOCYANINES; DSC;

D O I：

10.1007/BF01029664

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The template synthesis of copper(II) phthalocyanine by the condensation of dicyanobenzene within the supercages of Cu(II) exchanged X and Y type zeolites was studied using differential scanning calorimetry. The exotherms for intrazeolite and surface complexation have been resolved. These thermal events exhibit a dependence on the copper loading and hydration level which has been interpreted as a pressure effect.

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页码：163 / 169

页数：7

相关论文

共 20 条

[1] THE ENCAPSULATION OF RH(III) PHTHALOCYANINES IN ZEOLITE-X AND ZEOLITE-Y [J].

BALKUS, KJ ;

WELCH, AA ;

GNADE, BE .

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1991, 10 (01) :141-151

[2] APPLICATION OF DIFFERENTIAL SCANNING CALORIMETRY IN THE STUDY OF INTRAZEOLITE METALLOPHTHALOCYANINES [J].

BALKUS, KJ ;

FERRARIS, JP .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (21) :8019-8020

[3]

Berezin B. D., 1981, COORDINATION COMPOUN

[4] AN INVESTIGATION INTO THE MECHANISM OF THE PHTHALONITRILE ROUTE TO COPPER PHTHALOCYANINES USING DIFFERENTIAL SCANNING CALORIMETRY [J].

CHRISTIE, RM ;

DEANS, DD .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1989, (02) :193-198

[5]

DIEGRUBER H, 1984, J MOL CATAL, V24, P115

[6] MOBILITY OF CATIONS IN SYNTHETIC ZEOLITES WITH FAUJASITE FRAMEWORK .7. MOBILITY OF COPPER IN X AND Y ZEOLITES [J].

DYER, A ;

BARRI, SAI .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1977, 39 (06) :1061-1063

[7] HIGH-PRESSURE CONDITIONS FOR IMPROVED SYNTHESIS OF PHTHALOCYANINES [J].

EDMONDSON, SJ ;

HILL, JS ;

ISAACS, NS ;

MITCHELL, PCH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (03) :1115-1118

[8]

GABRIELOV AG, 1988, KOORDINATS KHIM+, V14, P821

[9] THE SELECTIVE PARTIAL OXIDATION OF ALKANES USING ZEOLITE BASED CATALYSTS - PHTHALOCYANINE (PC) SHIP-IN-BOTTLE SPECIES [J].

HERRON, N .

JOURNAL OF COORDINATION CHEMISTRY, 1988, 19 (1-3) :25-38

[10] SHAPE SELECTIVITY IN HYDROCARBON OXIDATIONS USING ZEOLITE ENCAPSULATED IRON PHTHALOCYANINE CATALYSTS [J].

HERRON, N ;

STUCKY, GD ;

TOLMAN, CA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (20) :1521-1522