DESULFURIZATIVE CYCLOPROPANATION OF 2-(1-ALKENYL)-1,3-DITHIANES AND SUBSTITUTED 1,3-BIS(PHENYLTHIO)-1-PROPENES WITH TITANOCENE-OLEFIN COMPLEXES

被引：18

作者：

HORIKAWA, Y ^{[1
]}

NOMURA, T ^{[1
]}

WATANABE, M ^{[1
]}

MIURA, I ^{[1
]}

FUJIWARA, T ^{[1
]}

TAKEDA, T ^{[1
]}

机构：

[1] TOKYO UNIV AGR & TECHNOL,DEPT APPL CHEM,KOGANEI,TOKYO 184,JAPAN

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 48期

关键词：

D O I：

10.1016/0040-4039(95)01887-N

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of 2-(1-alkenyl)-1,3-dithianes with the titanocene-olefin complexes, prepared by the reaction of titanocene dichloride with 2 equiv of alkyllithiums, in the presence of triphenyl-phosphine gave 1-alkenylcyclopropanes in good yields. The similar reaction of substituted 1,3-bis(phenylthio)-1-propenes also proceeded to produce the cyclopropanes.

引用

页码：8835 / 8838

页数：4

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