STRUCTURE OF A MIXED-VALENCE COPPER COMPLEX WITH 1,10-PHENANTHROLINE AND PSEUDOHALOGENIDE LIGANDS

被引：7

作者：

DUNAJJURCO, M

KABESOVA, M

KETTMANN, V

CISAROVA, I

MIKLOS, D

机构：

[1] COMENIUS UNIV BRATISLAVA, FAC PHARM, DEPT ANALYT CHEM, CS-83232 BRATISLAVA, CZECHOSLOVAKIA

[2] CZECHOSLOVAK ACAD SCI, INST PHYS, CS-18040 PRAGUE 8, CZECHOSLOVAKIA

[3] SLOVAK ACAD SCI, INST INORGAN CHEM, CS-84236 BRATISLAVA, CZECHOSLOVAKIA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270193000745

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of Cu(NO3)2, NH4OH, 1,10-phenanthroline (phen), KSCN and KSeCN in the molar ratio 1:10:2:2:2 in a water-ethanol solution gives a new mixed-valence compound, mu-cyano-1 kappaN:2kappaC-(seleno,thio)cyanato-2kappaN-tris(1, 10-phenanthroline)-1kappa4N,N';2kappa2N,N'-dicopper(I,II) (seleno,thio)-cyanate semiethanolate, for which the X-ray structure analysis reveals the composition [Cu(II)-Cu(I)(phen)3(CN)(SeCN)0.65(SCN)0.35]+(SeCN)0.45--(SCN)0.55.0.5C2H5OH. The [Cu(II)(phen)2]2+ and [Cu(I)(phen){(Se,S)CN}] moieties are bridged by CN-, giving rise to a binuclear cation with deformed trigonal-bipyramidal and deformed tetrahedral coordination for the bivalent and monovalent Cu atoms, respectively.

引用

页码：1476 / 1479

页数：4

共 8 条

[1] CRYSTAL AND MOLECULAR-STRUCTURE OF CYANOBIS(1,10-PHENANTHROLINE)COPPER(II) NITRATE MONOHYDRATE [J].