MULTIPARAMETRIC CURVE FITTING .14. MODUS-OPERANDI OF THE LEAST-SQUARES ALGORITHM MINOPT

被引:6
作者
MILITKY, J [1 ]
MELOUN, M [1 ]
机构
[1] UNIV CHEM TECHNOL PARDUBICE, DEPT ANALYT CHEM, CS-53210 PARDUBICE, CZECHOSLOVAKIA
关键词
D O I
10.1016/0039-9140(93)80333-M
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Hybrid least-squares algorithm MINOPT for a nonlinear regression is introduced. MINOPT from CHEMSTAT package combines fast convergence of the Gauss-Newton method in a vicinity of minimum with good convergence of gradient methods for location far from a minimum. Quality of minimization and an accuracy of parameter estimates for six selected models are examined and compared with different derivative least-squares methods of five commercial regression packages.
引用
收藏
页码:269 / 277
页数:9
相关论文
共 12 条
[1]  
Bard Y., 1974, NONLINEAR PARAMETER
[2]  
BATES DM, 1980, J ROY STAT SOC B MET, V42, P1
[3]   2 NEW UNCONSTRAINED OPTIMIZATION ALGORITHMS WHICH USE FUNCTION AND GRADIENT VALUES [J].
DENNIS, JE ;
MEI, HHW .
JOURNAL OF OPTIMIZATION THEORY AND APPLICATIONS, 1979, 28 (04) :453-482
[4]  
GALLANT AR, 1987, NONLINEAR STATISTICA
[5]  
Gill P. E., 1981, PRACTICAL OPTIMIZATI
[6]   MULTIPARAMETRIC CURVE FITTING .8. THE RELIABILITY OF DISSOCIATION-CONSTANTS ESTIMATED BY ANALYSIS OF ABSORBANCE-PH CURVES [J].
MELOUN, M ;
JAVUREK, M .
TALANTA, 1985, 32 (10) :973-986
[7]  
MELOUN M, 1992, CHEMOMETRICS INSTRUM, V1
[8]  
Meloun M., 1988, COMPUTATION SOLUTION
[9]  
MELOUN M, 1992, CHEMOMETRICS INSTRUM, V2
[10]  
MILITKY J, 1987, MAY P C CEF 87 TAORM