POLYIMIDES BY DIELS-ALDER POLYADDITION OF ALPHA-PYRONES

被引：14

作者：

ALHAKIMI, G ^{[1
]}

GORLS, H ^{[1
]}

KLEMM, E ^{[1
]}

机构：

[1] UNIV JENA,INST ORGAN CHEM & MAKROMOLEK CHEM,HUMBOLDTSTR 10,D-07743 JENA,GERMANY

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1994年 / 195卷 / 05期

关键词：

D O I：

10.1002/macp.1994.021950509

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

New linear polyimides 11 were synthesized via Diels-Alder addition polymerization of alpha-pyrones 9 with bismaleimides 10. The number-average molecular weights M(n)BAR range from 10000 to 34000 g . mol (gel-permeation chromatography). The chemical structure of these polymers is supported by X-ray crystallography, NMR spectra and model reactions. The Diels-Alder addition occurred with high endo selectivity.

引用

页码：1569 / 1576

页数：8