DIVALENT SILICON INTERMEDIATES

被引：154

作者：

ATWELL, WH

WEYENBER.DR

机构：

[1] Organometallic Research, Dow Corning Corporation, Midland, Michigan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1969年 / 8卷 / 07期

关键词：

Silanediyl; Silicon; Silylene;

D O I：

10.1002/anie.196904691

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Like carbenes, silylenes are assumed to occur as intermediates in many reactions. A detailed account of the reactivity of the silylenes is given and the reductive and thermolytic methods used for their preparation are discussed. Insertion and interception reactions emphasize the formal relationship between these species and the carbenes. Silacyclopropenes and silacyclopropanes have not, as yet, been isolated. Copyright © 1969 by Verlag Chemie, GmbH, Germany

引用

页码：469 / &

共 106 条

[1] KINETICS OF SILICON-SILICONTETRACHLORIDE REACTION IN A FLOW SYSTEM [J].