EXPERIMENTAL-MEASUREMENT OF VAPOR-LIQUID-EQUILIBRIUM IN ALCOHOL WATER SALT SYSTEMS

被引：56

作者：

MORRISON, JF ^{[1
]}

BAKER, JC ^{[1
]}

MEREDITH, HC ^{[1
]}

NEWMAN, KE ^{[1
]}

WALTER, TD ^{[1
]}

MASSIE, JD ^{[1
]}

PERRY, RL ^{[1
]}

CUMMINGS, PT ^{[1
]}

机构：

[1] UNIV VIRGINIA,DEPT CHEM ENGN,THORNTON HALL,CHARLOTTESVILLE,VA 22901

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1990年 / 35卷 / 04期

关键词：

Alcohols--Thermodynamic Properties - Electrolytes--Solutions - Thermodynamic Properties--Measurements - Thermodynamics--Mathematical Models;

D O I：

10.1021/je00062a007

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Vapor-liquid equilibrium measurements have been performed on a set of alcohol/water/salt solutions at atmospheric pressure with a modified Othmer still and a modified Boublík-Benson still. The systems studied are methanol and water with NaCl, NaBr, KCl, and KBr;1-propanol and water with NaCl, KBr, and NaBr; and 2-propanol with water and NaBr. The measurements are for salt concentrations ranging from infinite dilution to saturation for each water/alcohol solvent mixture. These experimental results constitute part of a database being developed to test theoretical models of mixed-solvent-electrolyte systems. © 1990, American Chemical Society. All rights reserved.

引用

页码：395 / 404

页数：10

共 31 条

[1]

BAKER JC, 1983, THESIS U VIRGINIA

[2] MOLAR EXCESS GIBBS FREE ENERGIES OF BENZENE-M-XYLENE MIXTURES [J].

BOUBLIK, T ;

BENSON, GC .

CANADIAN JOURNAL OF CHEMISTRY, 1969, 47 (04) :539-&

[3]

Chu J., 1950, DISTILLATION EQUILIB

[4] EXTRACTIVE DISTILLATION EMPLOYING A DISSOLVED SALT AS SEPARATING AGENT [J].

COOK, RA ;

FURTER, WF .

CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1968, 46 (02) :119-&

[5] LIQUID-VAPOUR EQUILIBRIA .29. MEASUREMENT OF EQUILIBRIUM DATA IN SYSTEMS WITH HIGH EQUILIBRIUM RATIO OF COMPONENTS [J].

DVORAK, K ;

BOUBLIK, T .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1963, 28 (05) :1249-&

[6]

FORBED RJ, 1970, SHORT HIST ART DISTI

[7]

Furter W.S., 1979, ADV CHEM SERIES, V177

[8] SALT EFFECT IN DISTILLATION - A LITERATURE REVIEW [J].

FURTER, WF ;

COOK, RA .

INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 1967, 10 (01) :23-&

[9] SALT EFFECT IN DISTILLATION - LITERATURE-REVIEW .2. [J].

FURTER, WF .

CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1977, 55 (03) :229-239

[10]

FURTER WF, 1968, CHEM ENG, pCE173

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