HYDROLYTIC BEHAVIOR OF GALLIUM(3) PERCHLORATE

被引:25
作者
CRAIG, HR
TYREE, SY
机构
[1] Department of Chemistry, College of William and Mary, Williamsburg, Virginia
关键词
D O I
10.1021/ic50073a037
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Solutions of gallium(III) perchlorate at different base-to-gallium ratios and equilibrated at 50 and 75° have been studied. The data, along with characterization of the solid phase as GaOOH, indicate that equilibrium can be represented by the equation GaOOH(c) + 3Haq+ ⇄ Gaaq,3+ + 2H2O. The polymerization of the gallium solute species during the lengthy periods leading up to equilibrium is found to be a function of the ionic strength, the base ratio, and the initial polymerization number. Such variable behavior does not affect the nature of the ultimate equilibrium species. © 1969, American Chemical Society. All rights reserved.
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页码:591 / &
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