THE REDUCTION OF THE NBX5/AIX3 SYSTEM WITH ALUMINUM IN THE PRESENCE OF AROMATIC-HYDROCARBONS - AN APPROACH TO NIOBIUM(II), NIOBIUM(I), AND NIOBIUM(0) ORGANOMETALLICS

被引：24

作者：

CALDERAZZO, F ^{[1
]}

PAMPALONI, G ^{[1
]}

ROCCHI, L ^{[1
]}

STRAHLE, J ^{[1
]}

WURST, K ^{[1
]}

机构：

[1] UNIV TUBINGEN,INST ANORGAN CHEM,W-7400 TUBINGEN 1,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 01期

关键词：

D O I：

10.1002/anie.199101021

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The niobium(0) compound [Nb(mes)2] (mes = 1,3,5-trimethylbenzene) was prepared not only by metal atom - ligand cocondensation, but also according to Equation (a). The chemical behavior of this compound is similar to that of the analogous complex [V(mes)2]. For example, it reacts under carbon monoxide atmosphere to give the green salt [Nb(mes)2(CO)] [Nb(CO)6]. This new, simple approach to niobium(0) compounds should facilitate their study (DME = dimethoxyethane).

引用

页码：102 / 103

页数：2

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