INFRARED AND RAMAN SPECTRA OF CYCLOPENTADIENYL-VANADIUM TETRACARBONYL DERIVATIVES - EVALUATION OF CARBON-OXYGEN FORCE CONSTANTS

被引：47

作者：

DURIG, JR

MARSTON, AL

KING, RB

HOUK, LW

机构：

[1] Department of Chemistry, University of South Carolina, Columbia, SC

[2] Department of Chemistry, University of Georgia, Athens, GA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 16卷 / 03期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0022-328X(00)89768-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Infrared (250-4000 cm-1) and laser Raman spectra (75-3300 cm-1) were obtained on C5H5V(CO)4 and CH3COC5H4V(CO)4. A vibrational assignment is proposed which is based upon the concept of local symmetry". The cyclopentadienyl ring breathing frequency was found to be associated with the strong sharp Raman line at 1117 cm-1. Force constants calculated for the carbonyl stretching vibrations were comparable to those of similar π-bonded metal carbonyls. © 1969."

引用

页码：425 / &

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