DERIVATIVES OF 2,3,4,5,6-PENTA-O-BENZYL-MYO-INOSITOL

被引：96

作者：

GIGG, R

WARREN, CD

机构：

[1] National Institute for Medical Research, London N.W.7, Mill Hill

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 18期

关键词：

D O I：

10.1039/j39690002367

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient synthesis of racemic 1,2-O-isopropylidene-myo-inositol is described. This compound was converted into racemic 2,3,4,5,6-penta-O-benzyl-myo-inositol by making use of the allyl ether group for protection. An optically active 2,3,4,5,6-penta-O-benzyl-myo-inositol was also obtained from galactinol. Racemic 2,3,4,5,6-penta-O-benzyl-myo-inositol monoesters of phthalic, succinic, phosphoric, phenylphosphoric, and benzyl-phosphoric acids were prepared for the purpose of resolution and as intermediates for a proposed synthesis of phosphatidylinositol.

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页码：2367 / &

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共 44 条

[1] CYCLITOLS .9. CYCLOHEXYLIDENE DERIVATIVES OF MYOINOSITOL [J].

ANGYAL, SJ ;

TATE, ME ;

GERO, SD .

JOURNAL OF THE CHEMICAL SOCIETY, 1961, (SEP) :4116-&

[2] CYCLITOLS .4. METHYL ETHERS OF MYOINOSITOL [J].

ANGYAL, SJ ;

GILHAM, PT .

JOURNAL OF THE CHEMICAL SOCIETY, 1957, (MAR) :1417-1422

[3] CYCLITOLS .12. FORMATION OF ISOPROPYLIDENE DERIVATIVES BY KETAL INTERCHANGE [J].

ANGYAL, SJ ;

HOSKINSON, RM .

JOURNAL OF THE CHEMICAL SOCIETY, 1962, (AUG) :2985-&

[4] CYCLITOLS .1. ISOPROPYLIDENE DERIVATIVES OF INOSITOLS AND QUERCITOLS - THE STRUCTURE OF PINITOL AND QUEBRACHITOL [J].

ANGYAL, SJ ;

MACDONALD, CG .

JOURNAL OF THE CHEMICAL SOCIETY, 1952, (FEB) :686-&

[5] CYCLITOLS .20. CYCLOHEXYLIDENE KETALS OF INOSITOLS [J].

ANGYAL, SJ ;

IRVING, GC ;

RUTHERFORD, D ;

TATE, ME .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (NOV) :6662-+

[6] CYCLITOLS .21. BENZYL ETHERS OF MYOINOSITOL . AROMATISATION OF TOSYL DERIVATIVE OF A MYOINOSITOL [J].

ANGYAL, SJ ;

TATE, ME .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (DEC) :6949-&

[7]

ANGYAL SJ, 1967, J CHEM SOC C, P919

[8] THE SYNTHESIS OF O-(L-ALPHA-GLYCERYLPHOSPHORYL)-ETHANOLAMINE AND SOME COMMENTS ON THE STEREOCHEMICAL ASPECTS OF THE BIOSYNTHESIS OF GLYCEROLPHOSPHATIDES FROM CARBOHYDRATES [J].

BAER, E ;

STANCER, HC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (18) :4510-4514

[9] THE ABSOLUTE CONFIGURATION OF THE MYO-INOSITOL 1-PHOSPHATES AND A CONFIRMATION OF THE BORNESITOL CONFIGURATIONS [J].

BALLOU, CE ;

PIZER, LI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (13) :3333-3335

[10] SYNTHESIS OF AN OPTICALLY ACTIVE MYO-INOSITOL 1-PHOSPHATE [J].

BALLOU, CE ;

PIZER, LI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (17) :4745-4745

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