UV PHOTOELECTRON-SPECTROSCOPY OF MATRIX-ISOLATED AND CONDENSED CO AND N2

被引：27

作者：

SCHMEISSER, D

JACOBI, K

机构：

[1] Fritz-Haber-Institut der Max-Planck-Gesellschaft

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 62卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)80411-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

UV photoelectron spectra of matrix-isolated and condensed CO and N2 have been measured. The emission from the 4σ, 1π and 5σ orbitals show similar relaxation shifts of about 1 eV. This shift is 0.3 eV larger for the species isolated in xenon matrices. The width of the peaks is smaller by 0.3 eV in the Xe matrix in comparison with the pure solids but remains larger than those measured for the gas phase. © 1979.

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页码：51 / 56

页数：6

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