REACTIVITY OF SMALL-RING MONOSTANNACYCLOALKANES .3. RING-EXPANSION REACTIONS OF 1,1-DIMETHYL-1-STANNACYCLOPENTANE

被引：8

作者：

BULTEN, EJ

BUDDING, HA

机构：

[1] Institute for Organic Chemistry TNO

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 166卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)82552-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

As a result of the enhanced reactivity of the endo-cyclic tincarbon bond 1,1-dimethyl-1-stannacyclopentane readily undergoes ring-expansion reactions with a variety of substrates to produce new organotin heterocycles. Illustrative examples include ring-expansion reactions with oxygen, sulphur, sulphur dioxide, diiron noncarbonyl, dichlorocarbene and diethyl azodicarboxylate. © 1979.

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页码：339 / 346

页数：8

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