DEALKOXYCARBONYLATIONS OF GEM DIESTERS AND BETA-KETOESTERS VIA AN ENZYME CATALYZED-HYDROLYSIS

被引：7

作者：

AHMAR, M

BLOCH, R

BORTOLUSSI, M

机构：

[1] Laboratoire des Carbocycles (Associé au C.N.R.S), Institut de Chi mi e Moléculaire d’Orsav, Université de Paris Sud, Bat. 420

来源：

SYNTHETIC COMMUNICATIONS | 1991年 / 21卷 / 8-9期

关键词：

D O I：

10.1080/00397919108019796

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new method for the dealkoxycarbonylation of malonate esters and beta-ketoesters, involving an enzyme catalyzed hydrolysis followed by a high temperature Kugelrohr distillation, is described.

引用

页码：1071 / 1074

页数：4

共 6 条

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[4] FACILE TRANSFORMATION OF SUBSTITUTED ALLYL MALONATES TO MONOCARBOXYLIC ACIDS AND ESTERS BY THE REACTION WITH AMMONIUM FORMATE CATALYZED BY PALLADIUM COMPLEXES
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[5] HYDROLYTIC ENZYMES IN ORGANIC-SYNTHESIS .2. ENZYMATIC-SYNTHESIS OF CHIRAL BUILDING-BLOCKS FROM PROCHIRAL SUBSTRATES - ENANTIOSELECTIVE SYNTHESIS OF MONOALKYL MALONATES
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[6] FACILE PALLADIUM-CATALYZED DECARBOXYLATION REACTION OF ALLYLIC BETA-KETO-ESTERS
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