OH(A2-SIGMA+) FRAGMENT EMISSION FROM REACTION OF ELECTRONICALLY EXCITED XE(6P) WITH H2O UNDER FREE JET AND BULB CONDITIONS

被引：5

作者：

HASHIMOTO, S

MATSUMI, Y

KAWASAKI, M

机构：

[1] Institute of Electronic Science, Hokkaido University, Sapporo

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 200卷 / 06期

关键词：

D O I：

10.1016/0009-2614(92)80100-P

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The state-selective energy transfer from two-photon excited Xe(6p) to H2O and the subsequent reaction has been studied by measurement of emission spectra of OH (A2SIGMA+ --> X2PI). The vibrational population ratios, N(v=1)/N(v=0), are 0.52 +/- 0.01 in a free jet and 0.37 +/- 0.02 in a bulb. This reveals the difference in dissociation dynamics following the intra-complex and the intermolecular electronic energy transfers from Xe(6p) to H2O.

引用

页码：624 / 630

页数：7

共 26 条

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