SYNTHESIS AND DEAMINATION OF 1-AMINO-4-BROMO-7,7-DIMETHYLBICYCLO[2.2.1]HEPTAN-2-OL

被引：5

作者：

LARSON, HO

OOI, TC

LUKE, WKH

EBISU, K

机构：

[1] Department of Chemistry, University of Hawaii, Honolulu

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 03期

关键词：

D O I：

10.1021/jo01255a009

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Deamination of the amino alcohol 9 leads to the formation of the bicyclo[2.1.1]hexane derivative 10. The amine 9 is available from the degradation of 2. Lead tetraacetate oxidation of the semicarbazone 6 yields the novel heterocycle 7 that hydrolyzes remarkably easily to the amine. © 1969, American Chemical Society. All rights reserved.

引用

页码：525 / &

共 25 条

[1]

BLATT AH, 1963, ORGANIC SYNTHESES ED, V2, P586

[2]

BOND FT, 1965, TETRAHEDRON LETT, P4685

[3] OXIDATIVE REACTIONS OF HYDRAZINES .4. ELIMINATION OF NITROGEN FROM 1,1-DISUBSTITUTED-2-ARENESULFONHYDRAZIDES [J].