SYNTHESIS OF (S)-(+)-PARASORBIC ACID AND (S)-(+)-2-TRIDECANOL ACETATE - BAKERS-YEAST REDUCTIONS OF GAMMA-KETOSULFONES AND DELTA-KETOSULFONES

被引：47

作者：

GOPALAN, AS

JACOBS, HK

机构：

[1] Department of Chemistry, Plant Genetic Engineering Lab New Mexico State University Las Cruces

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 39期

关键词：

D O I：

10.1016/S0040-4039(00)97900-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The enantioselective reduction of 4-(p-toluenesulfonyl) butane-2-one and 5-(p-toluenesulfonyl) pentane-2-one with bakers' yeast gave the corresponding (S) alcohols in high optical purities and moderately good yields. The alcohol 2a was converted to (S)(+)parasorbic acid (4), while 2b was used for the preparation of (S)(+)-2-tridecanol acetate (7), using short synthetic sequences. © 1990.

引用

页码：5575 / 5578

页数：4

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