TRANSITION-METAL MEDIATED THIATION OF AROMATIC RINGS

被引：69

作者：

DICKENS, MJ ^{[1
]}

GILDAY, JP ^{[1
]}

MOWLEM, TJ ^{[1
]}

WIDDOWSON, DA ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI & TECHNOL,DEPT CHEM,LONDON SW7 2AY,ENGLAND

来源：

TETRAHEDRON | 1991年 / 47卷 / 40期

关键词：

D O I：

10.1016/S0040-4020(01)82405-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three approaches to aromatic thiation have been studied. Dependent upon access to the necessary starting material, displacement of halogen in haloarenetricarbonylchromium(0) complexes by nucleophilic sulphur, quenching of lithiated arenetricarbonylchromium(0) complexes by electrophilic sulphur or palladium catalysed cross coupling of aryl iodides with alkylthiotrialkylstannanes were all effective and apparently general in scope. The latter is the preferred process.

引用

页码：8621 / 8634

页数：14

共 43 条

[41] UNSYMMETRICAL BIARYL SYNTHESIS - AN APPROACH TO NATURAL HIGHLY FUNCTIONALIZED BIARYLS VIA PALLADIUM CATALYZED COUPLING [J].

WIDDOWSON, DA ;

ZHANG, YZ .

TETRAHEDRON, 1986, 42 (07) :2111-2116

[42] ARENETRICARBONYLCHROMIUM(O) COMPLEXES IN ORGANIC-SYNTHESIS [J].

WIDDOWSON, DA .

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1988, 326 (1592) :595-610

[43] OXIDATION OF THIOLS BY DIMETHYL SULFOXIDE [J].

YIANNIOS, CN ;

KARABINOS, JV .

JOURNAL OF ORGANIC CHEMISTRY, 1963, 28 (11) :3246-&

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