SMI2-PROMOTED DEACETOXYLATION OF O-ACETYLSUGAR LACTONES - AN EASY ACCESS TO DEOXYSUGAR LACTONES

被引：39

作者：

INANAGA, J ^{[1
]}

KATSUKI, J ^{[1
]}

YAMAGUCHI, M ^{[1
]}

机构：

[1] KYUSHU UNIV, DEPT CHEM, FUKUOKA 812, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 06期

关键词：

D O I：

10.1246/cl.1991.1025

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selective deacetoxylation of O-acetylsugar lactones and O-acetyl-3-deoxysugar lactones was accomplished at room temperature with the aid of SmI2 in the presence of pivalic acid or acetic acid to give the corresponding alpha,beta-unsaturated lactones and saturated lactones (2,3-dideoxysugar derivatives), respectively.

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页码：1025 / 1026

页数：2

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