SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [(PTA)(3)AU]AU-2(2)(I-MNT)(2)CENTER-DOT-0.5ME(2)CO-CENTER-DOT-0.5MECN - AN EXAMPLE OF UNSUPPORTED AU-1 ... AU-1 INTERACTIONS WITH [AU(PTA)(3)]+, GIVING A NONLINEAR TETRANUCLEAR CHAIN (PTA=PHOSPHATRIAZAADAMANTANE, I-MNT=[S2C2(CN)(2)](2-))

被引：40

作者：

FACKLER, JP

STAPLES, RJ

ASSEFA, Z

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 04期

关键词：

D O I：

10.1039/c39940000431

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The water soluble complex [Au(pta)(3)]Cl reacts with K-2[i-mnt] to give a non-linear, tetranuclear Au chain complex with an unprecedented structure. e, i-mnt = [S2C2(CN)(2)](2-)}/

引用

页码：431 / 432

页数：2

共 19 条

[1] A NOVEL 3-CO-ORDINATE DI-GOLD(I) DIPHOSPHINE COMPLEX [AU2(ME2PCH2PME2)3](BF4)2 0.5C7H8 - X-RAY CRYSTAL AND MOLECULAR-STRUCTURE [J].

BENSCH, W ;

PRELATI, M ;

LUDWIG, W .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (24) :1762-1763

[2] SYNTHESIS OF A MONOPHOSPHORUS ANALOG OF HEXAMETHYLENETETRAMINE [J].

DAIGLE, DJ ;

PEPPERMA.AB ;

VAIL, SL .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1974, 11 (03) :407-408

[3] SYNTHESES AND CHARACTERIZATION OF DINUCLEAR GOLD(I) RING AND OPEN-RING COMPLEXES CONTAINING SATURATED AND UNSATURATED DITHIOL BRIDGING LIGANDS AND PHOSPHINE OR BIS(DIPHOSPHINE) DONOR LIGANDS - CRYSTAL-STRUCTURES OF [AU2(MU-S(CH2)3S)(MU-DPPM)],[AU2(MU-MNT)(PPH3)2], [AU2(MU-S2C6H4)(PPH3)2], AND [AU4(MU-S2C6H3CH3)2(PET3)2] [J].

DAVILA, RM ;

ELDUQUE, A ;

GRANT, T ;

STAPLES, RJ ;

FACKLER, JP .

INORGANIC CHEMISTRY, 1993, 32 (09) :1749-1755

[4]

DELERNO JR, 1976, INORG CHEM, V15, P815

[5]

ELDER RC, 1981, J CHEM SOC CHEM COMM, P900, DOI 10.1039/c39810000900

[6] IS REGULAR TETRAHEDRAL GEOMETRY POSSIBLE IN GOLD(I)-PHOSPHINE COMPLEXES - X-RAY CRYSTAL-STRUCTURES OF 3 MODIFICATIONS OF (PPH3)4AU+BPH-4 [J].

JONES, PG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (21) :1031-1033

[7] PREPARATION AND CRYSTAL-STRUCTURE OF THE 4-CO-ORDINATE GOLD(I) COMPLEX CHLOROTRIS(TRIPHENYLPHOSPHINE)GOLD(I) [J].

JONES, PG ;

SHELDRICK, GM ;

MUIR, JA ;

MUIR, MM ;

PULGAR, LB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (10) :2123-2125

[8] SYNTHESES AND X-RAY STRUCTURAL CHARACTERIZATIONS OF 3-COORDINATE AU(I) AND AG(I) COMPLEXES WITH THE POTENTIALLY TETRADENTATE LIGAND TRIS(2-(DIPHENYLPHOSPHINO)ETHYL)AMINE (NP3) - [AU-2(NP3)(2)](BPH(4))(2), AU(NP3)PF6,AU(NP3)NO3, AG(NP3)NO3, AND AG(NP3)PF6 - THE AU(I) COMPOUNDS ARE LUMINESCENT [J].

KHAN, MNI ;

STAPLES, RJ ;

KING, C ;

FACKLER, JP ;

WINPENNY, REP .

INORGANIC CHEMISTRY, 1993, 32 (25) :5800-5807

[9] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [NORMAL-BU4N]2[AU2(I-MNT)2](I-MNT = 1,1-DICYANOETHYLENE-2,2-DITHIOLATE) AND ITS OXIDATIVE-ADDITION PRODUCTS [PH4AS]2[AU2(I-MNT)2CL2], [NORMAL-BU4N]2[AU2(I-MNT)2BR2], AND [NORMAL-BU4N][AU(I-MNT)2] - SPECTRAL STUDIES OF THE DISPROPORTIONATION OF [NORMAL-BU4N]2[AU2(I-MNT)2X2] (X = CL-, BR-, I-) INTO [NORMAL-BU4N][AUX2] AND [NORMAL-BU4N][AU(I-MNT)2]L [J].

KHAN, MNI ;

WANG, SN ;

FACKLER, JP .

INORGANIC CHEMISTRY, 1989, 28 (18) :3579-3588

[10] LUMINESCENT MONONUCLEAR GOLD(I) PHOSPHINES [J].

KING, C ;

KHAN, MNI ;

STAPLES, RJ ;

FACKLER, JP .

INORGANIC CHEMISTRY, 1992, 31 (15) :3236-3238

← 1 2 →