Structural features of the S-matrix for the rotational excitation of homonuclear diatomic molecules by atom impact: Close-coupled versus approximate computations

被引：52

作者：

Lester, William A., Jr. ^{[1
]}

Bernstein, Richard B. ^{[1
]}

机构：

[1] Univ Wisconsin, Inst Theoret Chem, Madison, WI 53706 USA

来源：

CHEMICAL PHYSICS LETTERS | 1967年 / 1卷 / 05期

关键词：

D O I：

10.1016/0009-2614(67)85051-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Numerical solution of 4, 9 and 16 close-coupled equations has indicated that reliable probabilities for nth order transitions are obtainable only if (n+ 1) th order transitions are included in the truncated set of coupled equations.

引用

页码：207 / 210

页数：4

共 18 条

[1] ROTATIONAL EXCITATION OF MOLECULAR HYDROGEN [J].

ALLISON, AC ;

DALGARNO, A .

PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1967, 90 (569P) :609-&

[2] THE THEORY OF SCATTERING BY A RIGID ROTATOR [J].

ARTHURS, AM ;

DALGARNO, A .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1960, 256 (1287) :540-551

[3] THERMAL SCATTERING OF ATOMS BY HOMONUCLEAR DIATOMIC MOLECULES [J].

BERNSTEIN, RB ;

DALGARNO, A ;

MASSEY, H ;

PERCIVAL, IC .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1963, 274 (1356) :427-+

[4] QUANTUM MECHANICAL (PHASE SHIFT) ANALYSIS OF DIFFERENTIAL ELASTIC SCATTERING OF MOLECULAR BEAMS [J].

BERNSTEIN, RB .

JOURNAL OF CHEMICAL PHYSICS, 1960, 33 (03) :795-804

[5] ROTATIONAL, VIBRATIONAL, AND ELECTRONIC ENERGY TRANSFER IN FLUORESCENCE OF NITRIC OXIDE [J].

BROIDA, HP ;

CARRINGTON, T .

JOURNAL OF CHEMICAL PHYSICS, 1963, 38 (01) :136-&

[6] ROTATIONAL EXCITATION OF H2 AND D2 BY H IMPACT [J].

DALGARNO, A ;

HENRY, RJW ;

ROBERTS, CS .

PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1966, 88 (561P) :611-&

[7] ROTATIONAL EXCITATION OF MOLECULAR HYDROGEN BY SLOW ELECTRONS [J].

DALGARNO, A ;

HENRY, RJW .

PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1965, 85 (546P) :679-&

[8]

DALGARNO A, 1964, ATOMIC COLLISION PRO, P914

[9] COLLISIONS PROCESSES NOT INVOLVING CHEMICAL REACTIONS - ROTATIONAL ENERGY TRANSFER IN MOLECULAR COLLISIONS - TRANSITIONS IN PARAHYDROGEN [J].

DAVISON, WD .

DISCUSSIONS OF THE FARADAY SOCIETY, 1962, (33) :71-&

[10] GENERAL DISTORTED-WAVE TREATMENT OF ROTATIONAL TRANSITIONS IN MOLECULAR COLLISIONS [J].

DAVISON, WD .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1964, 280 (1380) :227-+

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