MICROBIAL HYDROXYLATIONS OF FURTHER OCTALIN DERIVATIVES

被引：11

作者：

OUAZZANI, J

ARSENIYADIS, S

ALVAREZMANZANEDA, R

RUMBERO, A

OURISSON, G

机构：

[1] CNRS,INST CHIM SUBST NAT,F-91198 GIF SUR YVETTE,FRANCE

[2] LAB CHIM ORGAN SUBST NAT,F-67084 STRASBOURG,FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 17期

关键词：

ALLYLIC HYDROXYLATION; T-BU ETHER HYDROXYLATION; RHIZOPUS-ARRHIZUS;

D O I：

10.1016/0040-4039(91)85019-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The allylic hydroxylation of octalin derivatives with Rhizopus arrhizus proceeds with high to excellent yields, even in the presence of substituents such as acetate, phosphate, free ketone or dioxolane, but not a benzyl group. One of the Me groups of a t-Bu ether can be hydroxylated.

引用

页码：1983 / 1986

页数：4

共 7 条

[1]

ARSENIYADIS S, UNPUB

[2] BIOTRANSFORMATIONS OF DELTA-4-3-KETOSTEROIDS BY THE FUNGUS RHIZOPUS-ARRHIZUS [J].