RELATIVE BOND-DISSOCIATION ENERGIES FOR SOME NADH MODEL COMPOUNDS FROM HYDRIDE TRANSFER ELECTRON-TRANSFER EQUILIBRIA IN ACETONITRILE

被引：20

作者：

KLIPPENSTEIN, J ^{[1
]}

ARYA, P ^{[1
]}

WAYNER, DDM ^{[1
]}

机构：

[1] NATL RES COUNCIL CANADA,STEACIE INST MOLEC SCI,ORGAN REACT DYNAM GRP,OTTAWA K1A 0R6,ONTARIO,CANADA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 24期

关键词：

D O I：

10.1021/jo00024a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electrochemical oxidation potentials of a number of N-alkylpyridinyl radicals (measured using photomodulation voltammetry) were combined in a thermochemical cycle with hydride transfer equilibrium data to provide an estimate of the relative C-H bond dissociation enthalpies of the NADH model compounds.

引用

页码：6736 / 6737

页数：2

共 28 条

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