A NEW AND CONVENIENT PROCESS FOR PREPARATION OF OPTICALLY PURE ARYL 2-PYRIDYL SULFOXIDES

被引：13

作者：

SHIBUTANI, T ^{[1
]}

FUJIHARA, H ^{[1
]}

FURUKAWA, N ^{[1
]}

机构：

[1] UNIV TSUKUBA,DEPT CHEM,SAKURA,IBARAKI 305,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 25期

关键词：

D O I：

10.1016/0040-4039(91)80657-R

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alpha-lithiation of aryl 12-pyridyl sulfoxides, treatment with l-menthyl sulfinate, and desulfinylation with Grignard reagents gave optically pure aryl 2-pyridyl sulfoxides in moderate yields.

引用

页码：2947 / 2948

页数：2

共 8 条

[1]

ANDERSEN KK, 1962, TETRAHEDRON LETT, P93

[2] OPTICALLY ACTIVE SULFOXIDES . SYNTHESIS + ROTATORY DISPERSION OF SOME DIARYL SULFOXIDES [J].

ANDERSEN, KK ;

FOLEY, JW ;

GAFFIELD, W ;

PAPANIKOLAU, NE ;

PERKINS, RI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (24) :5637-+

[3]

BORTOLINI O, 1988, REV HETEROATOM CHEM, V1, P66

[4] REACTIONS OF PYRIDYL AND QUINOLYL SULFOXIDES WITH GRIGNARD-REAGENT - A CONVENIENT PREPARATION OF PYRIDYL AND QUINOLYL GRIGNARD-REAGENTS [J].

FURUKAWA, N ;

SHIBUTANI, T ;

MATSUMURA, K ;

FUJIHARA, H ;

OAE, S .

TETRAHEDRON LETTERS, 1986, 27 (33) :3899-3902

[5] PREPARATION OF BIPYRIDYL DERIVATIVES VIA ALPHA-LITHIATION OF PYRIDYL PHENYL SULFOXIDES, SUBSTITUTION WITH ELECTROPHILES AND CROSS-COUPLING REACTIONS WITH GRIGNARD-REAGENTS [J].

FURUKAWA, N ;

SHIBUTANI, T ;

FUJIHARA, H .

TETRAHEDRON LETTERS, 1989, 30 (50) :7091-7094

[6] PREPARATION OF PYRIDYL GRIGNARD-REAGENTS AND CROSS COUPLING REACTIONS WITH SULFOXIDES BEARING AZAHETEROCYCLES [J].

FURUKAWA, N ;

SHIBUTANI, T ;

FUJIHARA, H .

TETRAHEDRON LETTERS, 1987, 28 (47) :5845-5848

[7]

MIOSKOWSKI C, 1975, TETRAHEDRON LETT, P3341

[8] AN EFFICIENT ASYMMETRIC OXIDATION OF SULFIDES TO SULFOXIDES [J].

PITCHEN, P ;

DUNACH, E ;

DESHMUKH, MN ;

KAGAN, HB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (26) :8188-8193

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