SYNTHESIS OF FUNCTIONALIZED 1-ALKENYLBORONATES VIA HYDROBORATION-DEALKYLATION OF ALKYNES WITH DIISOPINOCAMPHEYLBORANE

被引：41

作者：

KAMABUCHI, A ^{[1
]}

MORIYA, T ^{[1
]}

MIYAURA, N ^{[1
]}

SUZUKI, A ^{[1
]}

机构：

[1] HOKKAIDO UNIV,FAC ENGN,DEPT APPL CHEM,SAPPORO,HOKKAIDO 060,JAPAN

来源：

SYNTHETIC COMMUNICATIONS | 1993年 / 23卷 / 20期

关键词：

D O I：

10.1080/00397919308012607

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydroborations of propargyl chloride, ethyl propiolate, 3-trimethyl-silyloxy-1-butyne, 1,1-diethoxy-2-propyne, 1-iodo- and 1-bromo-1-hexyne, and 1-bromo-3-chloro-1-propyne with diisopinocampheylborane 1, followed by dealkylation of the isopinocampheyl groups with acetaldehyde provide the corresponding 1-alkenylboronates in high yields with high regioselectivity.

引用

页码：2851 / 2859

页数：9

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