FABRICATION OF PATTERNED, ELECTRICALLY CONDUCTING POLYPYRROLE USING A SELF-ASSEMBLED MONOLAYER - A ROUTE TO ALL-ORGANIC CIRCUITS

被引:125
作者
GORMAN, CB
BIEBUYCK, HA
WHITESIDES, GM
机构
[1] Department of Chemistry, Harvard University, Cambridge
关键词
D O I
10.1021/cm00051a013
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper describes the use of patterned self-assembled monolayers to fabricate small, two-dimensional patterns of electrically functional polypyrrole on a gold electrode. These patterns can be transferred to an insulating polydimethylsiloxane substrate. Thin (10-100 mu m) polypyrrole wires retain their electrical conductivity over millimeter length scales. Interdigitated fingers of polypyrrole spaced 50 mu m apart are electrically insulated from one another. Polypyrrole can be electrochemically polymerized on patterns with size features of 2 mu m into films that are 200-400 nm thick.
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页码:526 / 529
页数:4
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