OXOVANADIUM .4. COMPLEXES WITH N-SALICYLIDENEAMINO ACIDS

被引：97

作者：

THERIOT, LJ

CARLISLE, GO

HU, HJ

机构：

[1] Chemistry Department, North Texas State University, Denton

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 09期

关键词：

D O I：

10.1016/0022-1902(69)80200-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of a series of new oxovanadium(IV) complexes of N-Salicylideneamino acids are described. These complexes are characterized as five coordinate compounds and have the general formula of VO(Sal:AA)(H2O). The ligand stands for bivalent tridentate Schiff bases derived from salicylaldehyde and various ∞-amino acids. Electronic spectra are interpreted using recently proposed ordering of vanadium d orbitals by Vanquickenborne and McGlynn: xy < xz,yz < x2-y2 < z2. © 1969.

引用

页码：2841 / &

共 6 条

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