ELECTROOXIDATION OF SULFUR IN MOLTEN ALCL3-NACL(63-37 MOLE PERCENT)

被引:34
作者
MARASSI, R [1 ]
MAMANTOV, G [1 ]
MATSUNAGA, M [1 ]
SPRINGER, SE [1 ]
WIAUX, JP [1 ]
机构
[1] UNIV TENNESSEE,DEPT CHEM,KNOXVILLE,TN 37916
关键词
anode; electrode; oxidation;
D O I
10.1149/1.2129010
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The electrooxidation of sulfur in AlCl3-NaCl (63-37 mole percent) has been investigated in the temperature range 150°250°C. The oxidation of sulfur proceeds from S8 to SCl3+ and involves intermediates S8+(S162+), S82+, and S(1). © 1979, The Electrochemical Society, Inc. All rights reserved.
引用
收藏
页码:231 / 237
页数:7
相关论文
共 44 条
[1]  
[Anonymous], 1975, ADV INORG CHEM
[2]  
[Anonymous], 1976, PROG INORG CHEM
[3]   SECONDARY REACTIONS IN CONTROLLED POTENTIAL COULOMETRY .2. SECONDARY ELECTRODE REACTIONS [J].
BARD, AJ ;
MAYELL, JS .
JOURNAL OF PHYSICAL CHEMISTRY, 1962, 66 (11) :2173-&
[4]   ELECTROCHEMICAL OXIDATION OF N,N,N',N'-TETRAMETHYLBENZIDINE IN MOLTEN SODIUM TETRACHLOROALUMINATE [J].
BARTAK, DE ;
OSTERYOUNG, RA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1975, 122 (05) :600-607
[5]  
BJERRUM NJ, 1978, CHARACTERIZATION SOL, P251
[6]   ELECTROCHEMICAL BEHAVIOR OF SULFIDE IN FUSED LICL-KCL EUTECTIC [J].
BODEWIG, FG ;
PLAMBECK, JA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1969, 116 (05) :607-&
[7]   SOLVENT EQUILIBRIA OF ALCL3-NACL MELTS [J].
BOXALL, LG ;
JONES, HL ;
OSTERYOUNG, RA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1973, 120 (02) :223-231
[8]  
DELARUE G, 1960, B SOC CHIM FR, V906, P1654
[9]   CHLOROALUMINATE EQUILIBRIA IN ALCL3-NACL MELTS [J].
FANNIN, AA ;
KING, LA ;
SEEGMILLER, DW .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1972, 119 (07) :801-+
[10]   LOWER OXIDATION-STATES OF SULFUR .1. SPECTROPHOTOMETRIC STUDY OF SULFUR-CHLORINE SYSTEM IN MOLTEN NACL-ALCL3 (37-63 MOL-PERCENT) AT 150-DEGREES-C [J].
FEHRMANN, R ;
BJERRUM, NJ ;
POULSEN, FW .
INORGANIC CHEMISTRY, 1978, 17 (05) :1195-1200