FRAGMENTATION RECOMBINATION REACTIONS OF THE ELECTRON-RICH BINUCLEAR HYDRIDE [(PR(I)2PCH2CH2CH2PPR(I)2)RH]2(MU-H)2 WITH DIBENZYLZINC - X-RAY STRUCTURE OF [(PR(I)2PCH2CH2CH2PPR(I)2)RH]2(MU-H)2(MU-ZNCH2PH)2

被引：28

作者：

FRYZUK, MD

MCCONVILLE, DH

RETTIG, SJ

机构：

[1] Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 04期

关键词：

D O I：

10.1021/om00118a088

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Summary: The reaction of Zn(CH2Ph)2 with [(dippp)-Rh]2(µ-H)2 generates two rhodium-containing products, (η3-CH2Ph)Rh(dippp) and the tetranuclear derivative [(dippp)Rh]2(µ-H)2(µ-ZnCH2Ph)2, the latter presumably via initial oxidative addition of a zinc benzyl moiety and unsymmetrical fragmentation to mononuclear species followed by recombination and loss of H2. © 1990, American Chemical Society. All rights reserved.

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页码：1359 / 1360

页数：2

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