A KINETIC AND MECHANISTIC STUDY OF THE BAYLIS-HILLMAN REACTION

被引：97

作者：

BODE, ML ^{[1
]}

KAYE, PT ^{[1
]}

机构：

[1] RHODES UNIV,DEPT CHEM,POB 94,GRAHAMSTOWN 6140,SOUTH AFRICA

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 40期

关键词：

D O I：

10.1016/0040-4039(91)80098-Q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of acrylate esters with pyridinecarboxaldehydes, in the presence of 3-hydroxyquinuclidine or 1,4-diazabicyclo[2.2.2] octane, have been followed by H-1 NMR spectroscopy, and a mechanism which accommodates the kinetic data has been presented.

引用

页码：5611 / 5614

页数：4

共 8 条

[1] AMEER F, 1986, S AFR J CHEM, V39, P57
[2] NECIC ACID SYNTHONS .5. TOTAL SYNTHESIS OF (+/-)-RETRONECIC ACID AND RELATED-COMPOUNDS VIA ZINC-MEDIATED COUPLING OF HALOGENO-ESTERS
AMEER, F
DREWES, SE
HOOLE, R
KAYE, PT
PITCHFORD, AT
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1985, (12): : 2713 - 2717
[3] RATE ENHANCEMENT EFFECTS IN THE DABCO CATALYZED SYNTHESIS OF HYDROXYALKENOATE ESTERS
AMEER, F
DREWES, SE
FREESE, S
KAYE, PT
[J]. SYNTHETIC COMMUNICATIONS, 1988, 18 (05) : 495 - 500
[4] [Anonymous], [No title captured], Patent No. [2155113A1, 2155113]
[5] NECIC ACID SYNTHONS .1. TOTAL SYNTHESIS OF INTEGERRINECIC ACID
DREWES, SE
EMSLIE, ND
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1982, (09): : 2079 - 2083
[6] SYNTHETIC POTENTIAL OF THE TERTIARY-AMINE-CATALYSED REACTION OF ACTIVATED VINYL CARBANIONS WITH ALDEHYDES
DREWES, SE
ROOS, GHP
[J]. TETRAHEDRON, 1988, 44 (15) : 4653 - 4670
[7] DABCO-CATALYZED COUPLING OF ALDEHYDES WITH ACTIVATED DOUBLE-BONDS .4. STEREOSELECTIVE SYNTHESIS OF TRISUBSTITUTED OLEFINS AND TERPENOID BUILDING-BLOCKS VIA 2-(HYDROXYALKYL)-2-PROPENOIC ESTERS
HOFFMANN, HMR
RABE, J
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (20) : 3849 - 3859
[8] 1,4-DIAZOBICYCLO[2.2.2]OCTANE-CATALYZED COUPLING OF ALDEHYDES AND ACTIVATED DOUBLE-BONDS .3. A SHORT AND PRACTICAL SYNTHESIS OF MIKANECIC ACID (4-VINYL-1-CYCLOHEXENE-1,4-DICARBOXYLIC ACID)
HOFFMANN, HMR
RABE, J
[J]. HELVETICA CHIMICA ACTA, 1984, 67 (02) : 413 - 415

← 1 →