A 1,2-SILICON SHIFT IN CYCLOPROPYLIDENES LEADING TO 1-TRIALKYLSILYLCYCLOPROPENES

被引：17

作者：

BAIRD, MS

DALE, CM

ALDULAYYMI, JR

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 13期

关键词：

D O I：

10.1039/p19930001373

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,1-Dibromo-2-trialkylsilylcyclopropanes, readily prepared by dibromocyclopropanation of vinyltrialkyl-silanes, react with methyllithium at -90 to 20-degrees-C to give high yields of trialkylsilylcyclopropenes in which the silicon has apparently migrated to C-1.

引用

页码：1373 / 1374

页数：2

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