HYDROGEN-BONDING OF THE AMMONIUM ION

被引：29

作者：

BROWN, RJC

机构：

[1] University Chemical Laboratory, University of Cambridge, Cambridge, CB2 1EW, Lensfield Road

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1995年 / 345卷

关键词：

D O I：

10.1016/0022-2860(94)08381-Q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrogen bonding of ammonium ions in crystals is discussed, using evidence based upon the N-H bond length, vibrational frequencies, the activation energy for rotation, theoretical results on ammonium-water clusters and nuclear quadrupole coupling constants. The high symmetry environments found in crystals appear to inhibit hydrogen bond formation.

引用

收藏

页码：77 / 81

页数：5

相关论文

共 27 条

[1] OBSERVATION OF FORBIDDEN TRANSITIONS OF AMMONIUM ION (NH4+) V3 BAND AND DETERMINATION OF GROUND-STATE ROTATIONAL-CONSTANTS - OBSERVATION OF V3 BAND ALLOWED TRANSITIONS OF ND4+ [J].

CROFTON, MW ;

OKA, T .

JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (11) :5983-5988

[2] THE STRUCTURE OF (ND4)2CR(SO4)2.6D2O AT 4.3-K BY NEUTRON-DIFFRACTION [J].

FIGGIS, BN ;

KUCHARSKI, ES ;

FORSYTH, JB .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :419-421

[3] THE STRUCTURE OF (ND4)2FE(SO4)2.6D2O AT 4.3-K BY NEUTRON-DIFFRACTION [J].

FIGGIS, BN ;

KUCHARSKI, ES ;

REYNOLDS, PA ;

TASSET, F .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 :942-944

[4]

HADZI D, 1976, HYDROGEN BOND, P565

[5] LOW TEMPERATURE INFRARED AND RAMAN SPECTRA OF AMMONIUM HALIDES [J].

HARVEY, KB ;

MCQUAKER, NR .

JOURNAL OF CHEMICAL PHYSICS, 1971, 55 (09) :4390-&

[6] NATURE, GEOMETRY, AND BINDING STRENGTH OF THE AMMONIA-HYDROGEN CHLORIDE DIMER DETERMINED FROM THE ROTATIONAL SPECTRUM OF AMMONIUM-CHLORIDE VAPOR [J].

HOWARD, NW ;

LEGON, AC .

JOURNAL OF CHEMICAL PHYSICS, 1988, 88 (08) :4694-4701

[7] THE THERMOCHEMISTRY OF AMMONIUM-COMPOUNDS AND THE ENERGY BARRIER OPPOSING AMMONIUM ION REORIENTATION [J].

JOHNSON, DA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (02) :445-450

[8] THEORETICAL CHARACTERIZATION OF THE ROTATIONAL MOTION OF NH4+ IN WATER CLUSTERS [J].

KASSAB, E ;

EVLETH, EM ;

HAMOUTAHRA, ZD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (01) :103-108

[9]

KORPPITOMMOLA J, 1978, J RAMAN SPECTROSC, V11, P363

[10] NEUTRON-DIFFRACTION STUDY OF NUCLEAR DISTRIBUTIONS IN NH4CL [J].

KURKISUONIO, K ;

MERISALO, M ;

VAHVASELKA, A ;

LARSEN, FK .

ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (JAN1) :110-115