1-ALKYL-2,5-(ORTHO-PHENYLENE)-1-CARBAPENTABORANE(10)

被引：15

作者：

GANGNUS, B

STOCK, H

SIEBERT, W

HOFMANN, M

SCHLEYER, PV

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,D-69120 HEIDELBERG,GERMANY

[2] UNIV ERLANGEN NURNBERG,INST ORGAN CHEM 1,CTR COMP CHEM,D-91052 ERLANGEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 22期

关键词：

D O I：

10.1002/anie.199422961

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An unexpected result was obtained from the reaction of 1 with borane. Instead of the nido‐carborane 2, the arachno‐carborane 3 was formed in more than 80% yield. The structural characterization is based on the comparison of experimental NMR data with those calculated at the ab initio level. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2296 / 2298

页数：3

共 18 条

[1]

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[2] DECISIVE ELECTRON CORRELATION-EFFECTS ON COMPUTED B-11 AND C-13 NMR CHEMICAL-SHIFTS - APPLICATION OF THE GIAO-MP2 METHOD TO BORANES AND CARBABORANES [J].