STABLE PALLADIUM(0) AND PALLADIUM(II) COMPLEXES CONTAINING A NEW, MULTIFUNCTIONAL AND SEMI-LABILE PHOSPHORUS-BISNITROGEN LIGAND

被引：58

作者：

WEHMAN, P ^{[1
]}

RULKE, RE ^{[1
]}

KAASJAGER, VE ^{[1
]}

KAMER, PCJ ^{[1
]}

KOOIJMAN, H ^{[1
]}

SPEK, AL ^{[1
]}

ELSEVIER, CJ ^{[1
]}

VRIEZE, K ^{[1
]}

VANLEEUWEN, PWNM ^{[1
]}

机构：

[1] UNIV UTRECHT,BIJVOET CTR BIOMOLEC RES,CRYSTAL & STRUCT CHEM LAB,3584 CH UTRECHT,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 03期

关键词：

D O I：

10.1039/c39950000331

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new, multifunctional, semi-labile phosphorus-bisnitrogen ligand N-(2-diphenylphosphinobenzylidene)-2-(2-pyridyl)ethylamine, PNN, stabilises methyl(chloro)-,eta(1)-allyl(chloro)-, dichloro- and bis(tetrafluoroborate)-palladium(ii) PNN complexes in a terdentate coordination fashion, resulting in ionic palladium complexes, as well as an unprecedented palladium(0) PNN complex as is evidenced from H-1, C-13, P-31 and N-15 NMR spectra and an X-ray structural analysis of [(PNN)PdMe](+)[CI](-).

引用

页码：331 / 332

页数：2

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