SPECTROSCOPIC IDENTIFICATION OF BASIC NITROGEN COMPOUNDS IN WILMINGTON PETROLEUM

被引:30
作者
BRANDENBURG, CF
LATHAM, DR
机构
[1] Chemistry Department, University of Wyoming, Laramie
[2] Laramie Petroleum Research Center, Bureau of Mines, U. S. Department of the Interior, Laramie
关键词
D O I
10.1021/je60038a027
中图分类号
O414.1 [热力学];
学科分类号
摘要
A study of the basic nitrogen compounds in Wilmington (Calif.) petroleum fractions has produced considerable information on their composition. Characterization of the classes of basic nitrogen compounds in the 130° to 350° C. distillate fractions was made by low-voltage mass spectral analyses. Two individual compounds-an alkyl-substituted cyclopentapyrindan and an alkylcycloalkyl-substituted pyridine-were separated and identified. Procedures used to separate the compounds from the oil included distillation, mineral acid extraction, and gas-liquid chromatography. The identifications were made by a combination of mass, infrared, ultraviolet, and nuclear magnetic resonance spectrometry. © 1968, American Chemical Society. All rights reserved.
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页码:391 / +
页数:1
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