OSCILLATOR STRENGTHS AND ROTATIONAL STRENGHTS IN HARTREE-FOCK THEORY

被引：142

作者：

HARRIS, RA

机构：

[1] Department of Physics, University of California, Berkeley

[2] Department of Chemistry, University of California, Berkeley

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 50卷 / 09期

关键词：

D O I：

10.1063/1.1671653

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The various expressions for oscillator strengths and rotational strengths are examined within the context of Hartree-Fock theory. They are shown to be inequivalent. The f-sum rule, rotational sum rule, and the origin dependence of rotational strengths are also examined. It is shown that the time-dependent Hartree-Fock theory removes the difficulties.

引用

页码：3947 / &

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