NON QUASI-STATIONARY STATE PYROLYSIS - KINETIC-PARAMETERS OF NEOPENTANE PYROLYSIS MECHANISM

被引：15

作者：

MARQUAIRE, PM

COME, GM

机构：

[1] Institut National Polytechnique de Lorraine E.R.A. no 135 du C.N.R.S., E.N.S.I.C., Nancy Cedex, 54042, 1, rue Grandville

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1978年 / 9卷 / 02期

关键词：

D O I：

10.1007/BF02068919

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The study of neopentane pyrolysis during its induction period has allowed to determine, from the quantitative measurement of major primary products only, the rate constant of the limiting chain propagation step, as well as the kinetic parameters of initiation and termination steps. © 1978 Akadémiai Kiadó.

引用

页码：171 / 175

页数：5

共 11 条

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[3] SELF-INHIBITED PYROLYSIS OF NEOPENTANE AT SMALL EXTENTS OF REACTION [J].

HALSTEAD, MP ;

KONAR, RS ;

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MARSHALL, RM ;

PURNELL, JH .

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[4]

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[5]

MARQUAIRE PM, 1977, 5TH INT S GAS KIN MA

[6]

MARQUAIRE PM, 1976, THESIS NANCY

[7]

Mulcahy M.F.R, 1973, GAS KINETICS

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MULLER, J ;

BARONNET, F ;

SCACCHI, G ;

DZIERZYNSKI, M ;

NICLAUSE, M .

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1977, 9 (03) :425-449

[9] STUDY OF SPECTRA AND RECOMBINATION KINETICS OF ALKYL RADICALS BY MOLECULAR MODULATION SPECTROMETRY .2. RECOMBINATION OF ETHYL, ISOPROPYL AND TERT-BUTYL RADICALS AT ROOM-TEMPERATURE AND TERT-BUTYL RADICALS BETWEEN 250 AND 450 K [J].

PARKES, DA ;

QUINN, CP .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1976, 72 :1952-1971

[10]

RONDEAU JA, 1976, ACS SYM SER, V32, P131

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