REACTION OF SINGLET OXYGEN WITH ALKENYLIDENECYCLOPROPANES - IMPLICATION FOR A PEROXYALLYL INTERMEDIATE

被引：29

作者：

AKASAKA, T ^{[1
]}

MISAWA, Y ^{[1
]}

ANDO, W ^{[1
]}

机构：

[1] UNIV TSUKUBA,DEPT CHEM,TSUKUBA,IBARAKI 305,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 08期

关键词：

D O I：

10.1016/S0040-4039(00)88757-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photosensitized oxygenation of adamantenylidenecyciopropanes (1) gave either the corresponding oxetanones (2a-c) or the cyclic ketones (4 and 5) depending on the substituent on the cyclopropane ring in addition to adamantanone. The results are rationalized in terms of initial formation of a perepoxide followed by that of a peroxyallyl intermediate. © 1990.

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页码：1173 / 1176

页数：4

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