THERMODYNAMICS OF VERY CONCENTRATED AQUEOUS-ELECTROLYTES - LICL, ZNCL2, AND ZNCL2-NACL AT 25-DEGREES-C

被引：29

作者：

ANSTISS, RG

PITZER, KS

机构：

[1] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

[2] UNIV CALIF BERKELEY LAWRENCE BERKELEY LAB,BERKELEY,CA 94720

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1991年 / 20卷 / 09期

关键词：

THERMODYNAMICS; ELECTROLYTE SOLUTIONS; OSMOTIC COEFFICIENTS; ACTIVITY COEFFICIENTS;

D O I：

10.1007/BF01074948

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effectiveness of extended ion-interaction equations in the treatment of activity and osmotic coefficients for very concentrated electrolytes is explored for the examples LiCl-H2O, ZnCl2-H2O, and NaCl-ZnCl2-H2O. For the two pure electrolytes the results are very satisfactory. Although satisfactory agreement was also obtained for the solubility of NaCl in the ternary system, this is too limited a data base to justify general conclusions.

引用

页码：849 / 858

页数：10

共 16 条

[1] THERMODYNAMICS OF CONCENTRATED ELECTROLYTE MIXTURES .5. A REVIEW OF THE THERMODYNAMIC PROPERTIES OF AQUEOUS CALCIUM-CHLORIDE IN THE TEMPERATURE-RANGE 273.15-K-373.15-K [J].